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Mass-specific light absorption coefficients of natural aquatic particles in the near-infrared spectral region

机译:天然水生粒子在近红外光谱区域的质量比吸光系数

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摘要

The extent of light absorption in the near-infrared spectral region (NIR; 700-900 nm) of natural suspended particles was investigated by determining the absorption and mass-specific absorption coefficients of samples from different environments: river, coastal waters, tropical lagoon, and oceanic waters. Large amounts of sample were collected onto glass-fiber filters and measured inside the integrating sphere of a spectrophotometer. The absorption coefficient of particle suspension was also determined for visible wavelengths with a point-source integrating cavity absorption meter. Measurable nonzero particulate absorption in the NIR was determined in all samples, even in algal cultures. It was highest in the river samples (e.g., 1.7 m21 at 850 nm), reaching values similar to the NIR absorption of pure water--a strong NIR absorber. Lowest values were in oligotrophic waters and in algal cultures. Ratios of absorption at 750 nm to absorption at 442 and 672 nm varied between 2% to 30% and 3% to 80%, respectively. Mass-specific absorption in the NIR at 850 nm was also highest in the river (0.012 m2 g21) and lowest in oligotrophic waters (0.002-0.003 m2 g21). The observed NIR absorption can partly be explained by absorption of minerogenic particles, whereas the contribution of organic detritus to the NIR absorption is still mostly unknown.
机译:通过测定来自不同环境(河流,沿海水域,热带泻湖,和海洋水域。将大量样品收集到玻璃纤维过滤器上,并在分光光度计的积分球内部进行测量。还使用点源积分腔吸收仪确定了可见波长的颗粒悬浮液的吸收系数。在所有样品中,甚至在藻类培养物中,都确定了NIR中可测量的非零颗粒吸收。它在河流样品中最高(例如在850 nm处为1.7 m21),达到的值类似于纯水的NIR吸收-一种强大的NIR吸收剂。最低值出现在贫营养水域和藻类养殖中。 750 nm处的吸光率与442 nm和672 nm处的吸光率分别在2%至30%和3%至80%之间变化。 NIR在850 nm处的质量比吸收在河流中也最高(0.012 m2 g21),在贫营养水域中最低(0.002-0.003 m2 g21)。观察到的近红外吸收可以部分由成矿颗粒的吸收来解释,而有机碎屑对近红外吸收的贡献仍然未知。

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